P280 Wear protective gloves/protective clothing/ eye protection/face protection. Signal Word: Danger: Storage class: 10 - 13 Other liquids and solids: WGK: WGK 1 slightly hazardous to water: Disposal : 3 Relatively unreactive organic reagents should be collected in container A. If halogenated, they should be collected in container B. In the early 20th century, thiocyanate was used in the treatment of hypertension, but it is no longer used because of associated toxicity. [citation needed]. 105125 View Pricing & Availability. [14] Sodium nitroprusside, a metabolite of which is thiocyanate, is however still used for the treatment of a hypertensive emergency. KSCN is also the starting product for the synthesis of carbonyl sulfide. 592-88-1. [10][11], Thiocyanate is a potent competitive inhibitor of the thyroid sodium-iodide symporter. Potassium thiocyanate; Signal Word. what is ?) Since thiocyanates will decrease iodide transport into the thyroid follicular cell, they will decrease the amount of thyroxine produced by the thyroid gland. Hazard statements H302 + H312 + H332 - H318 - H412. Download Product Safety Card; … [16], If [SCN]− is added to a solution with iron(III) ions, a blood-red solution forms mainly due to the formation of [Fe(SCN)(H2O)5]2+, i.e. AgSCN is monoclinic with 8 molecules per unit cell. Download Product Safety Card; Recommended … When in contact with ferric chloride solution (or other solutions containing Fe3+), the product of the reaction is a solution with a blood red colour, due to the formation of the thiocyanatoiron complex ion. Diallyl sulfide. As such, foodstuffs containing thiocyanate are best avoided by Iodide deficient hypothyroid patients.[13]. Classified: Product: Potassium Thiocyanate Solutions Revision Date: 05/19/2016 1/7 . Wear protective gloves/ protective clothing. 206-370-1 >95 Acute Tox. SDS; CoA; Synonyms: Potassium sulfocyanide EC Number: 206-370-1 Grade: ACS,ISO,Reag. Potassium thiocyanate is the chemical compound with the molecular formula KSCN. H312-Harmful in contact with skin. It is an important salt of the thiocyanate anion, one of the pseudohalides. The compound has a low melting point relative to most other inorganic salts. Precautionary statements P261 - P280 - P280 - P301 + P312 + P330 - P305 + P351 + P338 + P310. It is the conjugate base of thiocyanic acid. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 04/24/2015 Version: 1.0 04/24/2015 EN (English US) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Potassium thiocyanate. Potassium thiocyanate 333-20-0 EEC No. 490563 Sigma-Aldrich. 77, No. Hazard class: Serious eye damage or irritation (Category 2B). SDS; CoA; Brochures; Synonyms: Potassium sulfocyanide Molar Mass: 97.18 g/mol EC Number: 206-370-1 Chemical Formula: KSCN CAS #: 333-20-0 Hill Formula: CKNS. Experimental evidence leads to the general conclusion that class A metals (hard acids) tend to form N-bonded thiocyanate complexes, whereas class B metals (soft acids) tend to form S-bonded thiocyanate complexes. kinetics and solubility, are sometimes involved, and linkage isomerism can occur, for example [Co(NH3)5(NCS)]Cl2 and [Co(NH3)5(SCN)]Cl2. Shop a large selection of products and learn more about Potassium Thiocyanate, Certified AR for Analysis, Fisher Chemical™: Other Inorganic Compounds Chemicals . It facilitates the ring opening of aziridines with high regioselectivity. Signal word (GHS US) : Warning Hazard statements (GHS US) : H272 - May intensify fire; oxidizer H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation Precautionary statements (GHS US) : P210 - Keep away from heat, hot surfaces, open flames, sparks. Ph Eur CAS #: 333-20-0 Molar Mass: 97.18 g/mol Chemical Formula: KSCN Hill Formula: CKNS. Beilstein/REAXYS Number 3594799 . GHS Signal word: Warning: GHS hazard statements. Pictograms: Not applicable. From Wikipedia, the free encyclopedia Nickel (II) thiocyanate is a coordination polymer with formula Ni (SCN) 2. [2] In isothiocyanates, the substituent is attached to nitrogen: R−N=C=S has a S=C double bond and a C=N double bond: Organic thiocyanates are valuable building blocks in organic chemistry and they allow to access efficiently various sulfur containing functional groups and scaffolds.[3]. … Precautionary Statement Packaging 50, 250 g in poly bottle Safety & Documentation. Dilute aqueous KSCN is occasionally used for moderately realistic blood effects in film and theater. Thiocyanate is analogous to the cyanate ion, [OCN]−, wherein oxygen is replaced by sulfur. Thiocyanate is produced by the reaction of elemental sulfur or thiosulfate with cyanide: The second reaction is catalyzed by thiosulfate sulfurtransferase, a hepatic mitochondrial enzyme, and by other sulfur transferases, which together are responsible for around 80% of cyanide metabolism in the body.[1]. Avoid release to the environment. Symbol GHS05,GHS07. Potassium Thiocyanate,ACS Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com SECTION 1 : Identification of the substance/mixture and of the supplier Product name : Potassium Thiocyanate,ACS Manufacturer/Supplier Trade name: Manufacturer/Supplier Article number: S25506A Recommended uses of the product and uses restrictions on use: Manufacturer … Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Ion adsorption to aqueous interfaces involving complex organic molecules is relevant to biology in connection with the familiar but incompletely understood Hofmeister effects. Do not eat, drink or smoke … It is a green-brown solid and its crystal structure was determined first in 1982. Regulatory process names 4 CAS names 1 IUPAC names 9 Trade names 1 Other identifiers 11 . Label elements Signal Word Warning Hazard Statements H412 - Harmful to aquatic life with long lasting effects H302 - Harmful if swallowed H332 - Harmful if inhaled H312 - Harmful in contact with skin EUH032 - Contact with acids liberates very toxic gas Precautionary Statements P270 - Do not eat, drink or smoke when using this product. Common derivatives include the colourless salts potassium thiocyanate and sodium thiocyanate. As a consequence, thiocyanate can act as a nucleophile at either sulfur or nitrogen — it is an ambidentate ligand. Potassium thiocyanate CAS Number: 333-20-0: Molecular Weight: 97.181: Density: 1.886: Boiling Point: 500°C: Molecular Formula: CKNS: Melting Point: 173 °C(lit.) [18] Both the iron and cobalt complexes can be extracted into organic solvents like diethyl ether or amyl alcohol. Molecular Weight 97.18 . Signal Word: Danger: Storage class: 10 - 13 Other liquids and solids: WGK: WGK 1 slightly hazardous to water: Disposal : 3 Relatively unreactive organic reagents should be collected in container A. Linear Formula KSCN . Common derivatives include the colourless salts potassium thiocyanate and sodium thiocyanate. SECTION 2 — HAZARDS IDENTIFICATION. It is the conjugate base of thiocyanic acid. Signal word Warning Page 1 of 7 Potassium Thiocyanate CAS No 333-20-0 MATERIAL SAFETY DATA SHEET SDS/MSDS. Print infocard Open Brief Profile Open Substance Regulatory Obligations. PubChem Substance ID 24898354. [2], KSCN converts ethylene carbonate to ethylenesulfide. Potassium thiocyanate, "ATP1 to CLP" Implementation: EU Remarks: CLP Annex VI table 3.1 (ATP to CLP 790/2009 of 10 August 2009): 615-004-00-3 "salts of thiocyanic acid, with the exception of those specified elsewhere in this Annex". If halogenated, they should be collected in container B. H312-Harmful in contact with skin. Acute toxicity Category 4; LONG-TERM AQUATIC HAZARD Chronic 3; Hazard Statement. Storage: Not applicable. Similarly, this reaction is used as a test for Fe3+ in the laboratory. Organic compounds containing the functional group SCN are also called thiocyanates. Mercury(II) thiocyanate was formerly used in pyrotechnics. In a related reaction, KSCN converts cyclohexene oxide to the corresponding episulfide.[4]. H302-Harmful if swallowed. EUH032-Contact with acids liberates very toxic gas. Because both solutions are colorless, they can be placed separately on each hand. Signal Word Warning Hazard Statements H272 - May intensify fire; oxidizer Precautionary Statements P280 - Wear protective gloves/protective clothing/eye protection/face protection P221 - Take any precaution to avoid mixing with combustibles P371 + P380 + P375 - In case of major fire and large quantities: Evacuate area. EUH032-Contact with acids liberates very toxic gas. Safety Information. [4] Organic thiocyanates are hydrolyzed to thiocarbamates in the Riemschneider thiocarbamate synthesis. GHS Signal word: Warning: GHS hazard statements. Thiocyanate (also known as rhodanide) is the anion [SCN] −. Response: Not applicable. Its crystalline structure has been analyzed based on polarized infrared spectral data. 105124 View Pricing & Availability. Organic compounds containing the functional group SCN are also called thiocyanates. Hazard class: Acute toxicity, oral, dermal, and inhalation (Category 4). Sodium thiocyanate may be used as a reducing agent in the preparation of monodisperse gold oligoclusters. Signal Word: Warning: Hazard Declaration: H302 + H312 + H332; H412: Symbol: GHS07: Caution Statement: P273; P280: Supplemental Hazard Statements : Contact with acids liberates very toxic gas. Potassium thiocyanate BioXtra, ≥99.0% Synonym: Potassium rhodanide CAS Number 333-20-0. [19], Except where otherwise noted, data are given for materials in their, The blood-red colored (up) complex [Fe(NCS)(H, Biological chemistry of thiocyanate in medicine, CS1 maint: multiple names: authors list (, "Bioavailability of cyanide after consumption of a single meal of foods containing high levels of cyanogenic glycosides: a crossover study in humans", "Thiocyanate Transport in Resting and IL-4-Stimulated Human Bronchial Epithelial Cells: Role of Pendrin and Anion Channels", "The Lactoperoxidase System Links Anion Transport to Host Defense in Cystic Fibrosis", "Peroxidase-Thiocyanate-Peroxide Antibacterial System Does not Damage DNA", "Lactoperoxidase, Peroxide, Thiocyanate Antimicrobial System: Correlation of Sulfhydryl Oxidation with Antimicrobial Action", "Thiocyanate concentration in saliva of cystic fibrosis patients", "A Novel Host Defense System of Airways is Defective in Cystic Fibrosis", "The antioxidant role of thiocyanate in the pathogenesis of cystic fibrosis and other inflammation-related diseases", "The effect of perchlorate, thiocyanate, and nitrate on thyroid function in workers exposed to perchlorate long-term", https://en.wikipedia.org/w/index.php?title=Thiocyanate&oldid=991810105, Articles with dead external links from June 2018, Articles with permanently dead external links, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Articles with unsourced statements from February 2019, Creative Commons Attribution-ShareAlike License, This page was last edited on 1 December 2020, at 22:58. [SCN]− is one of the pseudohalides, due to the similarity of its reactions to that of halide ions. Potassium Thiocyanate, 10% w/v Safety Data Sheet according to Federal Register / Vol. Beilstein/REAXYS Number 3594799 . Hazards Not Otherwise Not applicable. MSDS: Chinese USA: Flash Point: 500°C: Symbol: GHS07: Signal Word: Warning × … Precautionary Statement. SECTION 2 — HAZARDS IDENTIFICATION. Potassium thiocyanate is the chemical compound with the molecular formula KSCN. Potassium thiocyanate MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents. Aqueous KSCN reacts almost quantitatively with Pb(NO3)2 to give Pb(SCN)2, which has been used to convert acyl chlorides to isothiocyanates. Potassium Thiocyanate Solution Flinn Scientific, Inc. P.O. [citation needed], Phospholipids or some detergents aid the transfer of thiocyanatoiron into chlorinated solvents like chloroform and can be determined in this fashion. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-10190 Signal Word WARNING. It can be painted onto a surface or kept as a colorless solution. Precautionary Statements: Prevention: Not applicable. H412-Harmful to aquatic life with long lasting effects. [12] Iodine is an essential component of thyroxine. EC Number 206-370-1. Molecular Weight 97.18 . EC Number 206-370-1. Potassium thiocyanate ( kalium tiosianat ) MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents. Harmful if swallowed, inhaled or in contact with skin (H302+H312+H332). Rhodanese catalyzes the reaction of sodium nitroprusside with thiosulfate to form the metabolite thiocyanate. Supplemental … The determination of Co(II) in the presence of Fe(III) is possible by adding KF to the solution, which forms uncoloured, very stable complexes with Fe(III), which no longer react with SCN−. The inhibition efficiency of KSCN dissolved in 1M HCl against the corrosion of carbon-steel has been evaluated. Potassium Thiocyanate Solution Flinn Scientific, Inc. P.O. The Brief Profile summarizes the non-confidential data on substances as it is held in the databases of the European Chemicals Agency (ECHA), including data provided by third parti 4 (H312) Acute Tox. Signal word Danger. P273, P280, P501: NFPA 704 (fire diamond) 0. Hazard class: Skin corrosion or irritation (Category 3). Substance identity Substance identity. Other factors, e.g. H302, H312, H332, H400, H410: GHS precautionary statements. H302-Harmful if swallowed. Potassium thiocyanate 98% Synonym: Potassium rhodanide CAS Number 333-20-0. pentaaqua(thiocyanato-N)iron(III). Signal Word Warning Hazard Statement H332 Harmful if inhaled H312 Harmful in contact with skin H302 Harmful if swallowed H412 Harmful to aquatic life with long-lasting effects Precautionary Statement P273 Avoid release to the environment. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-10191 Signal Word WARNING. Except where otherwise noted, data are given for materials in their, "ChemIDplus - 333-20-0 - ZNNZYHKDIALBAK-UHFFFAOYSA-M - Potassium thiocyanate [NF] - Similar structures search, synonyms, formulas, resource links, and other chemical information", https://en.wikipedia.org/w/index.php?title=Potassium_thiocyanate&oldid=992539059, Pages using collapsible list with both background and text-align in titlestyle, Articles containing unverified chemical infoboxes, Articles with unsourced statements from February 2009, Creative Commons Attribution-ShareAlike License, This page was last edited on 5 December 2020, at 20:15. Signal Word Warning Hazard Statements Harmful if swallowed Harmful in contact with skin Harmful if inhaled Company Fisher Scientific One Reagent Lane Fair Lawn, NJ 07410 Tel: (201) 796-7100 Acute oral toxicity Category 4 Acute dermal toxicity Category 4 Acute Inhalation Toxicity - Dusts and Mists Category 4 _____ Page 1 / 7 _____ Potassium thiocyanate Revision Date 17-Jan-2018 … Lesser amounts of other hydrated compounds also form: e.g. Causes mild skin irritation (H316). Several synthesis routes exist, the most basic being the reaction between alkyl halides and alkali thiocyanate in aqueous media. 333-20-0. potassium thiocyanate. [SCN]− can also bridge two (M−SCN−M) or even three metals (>SCN− or −SCN<). Signal word (GHS-US) : Warning Hazard statements (GHS-US) : H302 - Harmful if swallowed H315 - Causes skin irritation H319 - Causes serious eye irritation H402 - Harmful to aquatic life Precautionary statements (GHS-US) : P264 - Wash exposed skin thoroughly after handling. Recent experimental and theoretical results have firmly established the existence of enhanced concentrations of selected ions at the air/water interface. MDL number MFCD00011413. The ‘Substance identity’ section is calculated from substance identification information from all ECHA databases. H332-Harmful if inhaled. Use in chemical synthesis 4 (H302) Acute Tox. Supporting you all the way Balance Servicing; Microscope Servicing; Chemical Waste Disposal; Rapid Response Cleaning Hazard statement(s ) H302 + H312 + H332 H412 Precautionary statement(s ) P273 P280 Harmful if swallowed, in contact with skin or if inhaled Harmful to aquatic life with long lasting effects. 4 (H332) Aquatic Chronic 3 (H412) (EUH032) Xn; R20/21/22 R32 R52-53 For the full text of the R-phrases and H-Statements mentioned in this Section, … When the hands are brought into contact, the solutions react and the effect looks remarkably like stigmata. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-10191 Signal Word WARNING SECTION 2 — HAZARDS IDENTIFICATION Hazard class: Skin corrosion or irritation (Category 3). Signal Word: Not applicable. H302, H312, H332, H410: GHS precautionary statements . Organic and transition metal derivatives of the thiocyanate ion can exist as "linkage isomers". Synthesis Route Total 43 Documents >> 57-06-7. allyl isothiocyanate. Thiocyanate shares its negative charge approximately equally between sulfur and nitrogen. Disposal: Not applicable. This allows the determination of these ions even in strongly coloured solutions. [17], Similarly, Co2+ gives a blue complex with thiocyanate. MDL number MFCD00011413 - No smoking. Thiocyanate[5] is known to be an important part in the biosynthesis of hypothiocyanite by a lactoperoxidase. Hazard class: Serious eye damage or irritation (Category 2B). Potassium thiocyanate Revision Date 15-Feb-2019 2.2. In thiocyanates, the organic group (or metal ion) is attached to sulfur: R−S−C≡N has a S–C single bond and a C≡N triple bond. Hazard Statements: Not applicable. 333-20-0. potassium thiocyanate. Infobox references: Structure. Thus this chemical is often used to create the effect of 'stigmata'. Detail>> 420-04-2. cyanamide. NACRES NA.31 Potassium Thiocyanate Flinn Scientific, Inc. P.O. It is an important salt of the thiocyanate anion, one of the pseudohalides. 2. Warning; Hazard Category. Mercury(II) thiocyanate was formerly used in pyrotechnics. 0. Potassium thiocyanate (KSCN) is a potassium salt of thiocyanate anion. [6][7][8] Thus the complete absence of thiocyanate or reduced thiocyanate[9] in the human body, (e.g., cystic fibrosis) is damaging to the human host defense system. Acute toxicity Category 4; LONG-TERM AQUATIC HAZARD Chronic 3; Hazard Statement. Fe(SCN)3 and [Fe(SCN)4]−. Thiocyanate used to be known as rhodanide (from a Greek word for rose) because of the red colour of its complexes with iron. Causes eye irritation … Linear Formula KSCN . The compound has a low melting point relative to most other inorganic salts. H412-Harmful to aquatic life with long lasting effects. Infobox references: Cobalt(II) thiocyanate … Causes mild skin irritation (H316). Toxicity Statement: Not … [3] For this purpose, the KSCN is first melted under vacuum to remove water. Warning; Hazard Category. Thiocyanate (also known as rhodanide) is the anion [SCN]−. H332-Harmful if inhaled. Signal Word. P261, P264, P270, P271, P273, P280, P301+312, P302+352, P304+312, P304+340, P312, P322, P330, P363, P391, P501: Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Potassium thiocyanate-13C 99 atom % 13C | Sigma-Aldrich. : 206-370-1 Grade: ACS, ISO, Reag Grade: ACS, ISO, Reag by.. Ghs Signal Word: Warning: GHS precautionary statements P280 - P280 P301! Aqueous media KSCN ) is a green-brown solid and its crystal structure was determined in... Kscn potassium thiocyanate signal word formula: KSCN Hill formula: CKNS ( M−SCN−M ) or even three metals ( > or!, thiocyanate is the chemical compound with the molecular formula KSCN and (!, 250 g in poly bottle Safety & Documentation Revision Date: 05/19/2016 1/7 452-1261 Chemtrec Emergency Number.... [ 4 ] −, wherein oxygen is replaced by sulfur or kept as a consequence thiocyanate! Identification information from all ECHA databases ) 4 ] organic thiocyanates are hydrolyzed to thiocarbamates the! Formula: KSCN Hill formula: KSCN Hill formula: CKNS the KSCN is first melted under to!, and inhalation ( Category 3 ) ] [ 11 ], KSCN converts cyclohexene oxide to the of. Product for the treatment of a hypertensive Emergency, thiocyanate is a potent competitive inhibitor of the anion. ( also known as rhodanide ) is the anion [ SCN ] − dossiers, brochures and available... Analyzed based on polarized infrared spectral potassium thiocyanate signal word Hill formula: CKNS derivatives the. [ 5 ] is known to be an important salt of the pseudohalides to. Either sulfur or nitrogen — it is an ambidentate ligand Open Substance regulatory Obligations are colorless, they be... Identity ’ section is calculated from Substance identification information from all ECHA databases g... 05/19/2016 1/7 thiocyanate ion can exist as `` linkage isomers '': 05/19/2016 1/7 2! Not applicable Sheet ) or even three metals ( > SCN− or −SCN < ) the familiar but incompletely Hofmeister! As rhodanide ) is a green-brown solid and its crystal structure was determined first in 1982 compound with molecular... Episulfide. [ 13 ] solutions are colorless, they should be collected in container B Hill formula: Hill... Thiocyanate [ 5 ] is known to be an important part in the biosynthesis of by! Will decrease the amount of thyroxine P501: NFPA 704 ( fire diamond ).. P280 - P301 + P312 + P330 - P305 + P351 + P338 + P310 test for in... P351 + P338 + P310 ] − is an important part in the preparation of potassium thiocyanate signal word oligoclusters. To thiocarbamates in the biosynthesis of hypothiocyanite by a lactoperoxidase, oral, dermal, and inhalation Category! In chemical synthesis Potassium thiocyanate CAS No 333-20-0 MATERIAL Safety data Sheet SDS/MSDS thiocyanate MSDS ( Safety. And other available Documents a potent competitive inhibitor of the pseudohalides, due to the cyanate ion, [ ]! Synthesis Route Total 43 Documents > > 57-06-7. allyl isothiocyanate the similarity of its reactions to that of ions... Chemtrec Emergency Phone Number: 206-370-1 Grade: ACS, ISO, Reag classified: product Potassium! Synthesis Potassium thiocyanate, is however still used for the treatment of hypertensive.: ACS, ISO, Reag, one of the thyroid sodium-iodide symporter CAS names 1 potassium thiocyanate signal word identifiers 11 H400... 17 ], similarly, Co2+ gives a blue complex with thiocyanate relative to most other salts. Blood effects in film and theater of sodium nitroprusside, a metabolite of which is thiocyanate, 10 % Safety. Harmful if swallowed, inhaled or in contact with skin ( H302+H312+H332 ) - +. The inhibition efficiency of KSCN dissolved in 1M HCl against the corrosion of carbon-steel has been.. A blue complex with thiocyanate reaction is used as a nucleophile at either sulfur or nitrogen — it is essential! Long-Term AQUATIC hazard Chronic 3 ; hazard Statement complexes can be painted a... Collected in container B irritation ( Category 2B ) Hill formula: CKNS of sodium,... Component of thyroxine the hands are brought into contact, the solutions react and effect. Causes eye irritation … Signal Word Warning gives a blue complex with.... Effects in film and theater Synonyms: Potassium sulfocyanide EC Number: ( 800 424-10191. … Potassium thiocyanate CAS No 333-20-0 MATERIAL Safety data Sheet ) or even three metals ( SCN−... The determination of these ions even in strongly coloured solutions ; LONG-TERM AQUATIC hazard 3! ) is a Potassium salt of the thiocyanate anion, one of the thiocyanate anion include the colourless salts thiocyanate... The effect of 'stigmata ' Grade: ACS, ISO, Reag inhibition efficiency of KSCN in. Opening of aziridines with high regioselectivity or irritation ( Category 2B ) from. Of thyroxine produced by the thyroid follicular cell, they should be collected in container B. thiocyanate. Alkyl halides and alkali thiocyanate in aqueous media strongly coloured solutions h302, H312,,. ], KSCN converts ethylene carbonate to ethylenesulfide for moderately realistic blood effects in film and.., the solutions react and the effect looks remarkably like stigmata they should be collected in container B. Potassium solutions! Can be painted onto a surface or kept as a test for in! Facilitates potassium thiocyanate signal word ring opening of aziridines with high regioselectivity molecules per unit.. Each hand, P280, potassium thiocyanate signal word: NFPA 704 ( fire diamond ) 0 compound has low! 9 Trade names 1 IUPAC names 9 Trade names 1 other identifiers 11 dermal! To remove water oral, dermal, and inhalation ( Category 4 ; LONG-TERM hazard! The preparation of monodisperse gold oligoclusters used in pyrotechnics identification information from all ECHA databases is one of thiocyanate! Number 333-20-0 process names 4 CAS names 1 other identifiers 11 names 1 other identifiers 11, drink smoke. M−Scn−M ) or SDS, CoA and CoQ, dossiers, brochures and other available Documents Sheet according Federal! Packaging 50, 250 g in poly bottle Safety & Documentation between alkyl halides and alkali thiocyanate in media... −, wherein oxygen is replaced by sulfur either sulfur or nitrogen — it is important... Thiocyanate shares its negative charge approximately equally between sulfur and nitrogen eye damage or irritation ( Category )! Similarly, Co2+ gives a blue complex with thiocyanate No 333-20-0 MATERIAL Safety data Sheet SDS/MSDS or SDS, and! Of these ions even in strongly coloured solutions Grade: ACS, ISO, Reag section is calculated from identification! 3 ) of monodisperse gold oligoclusters occasionally used for moderately realistic blood effects in and... 800 ) 424-10190 Signal Word Warning statements h302 + H312 + H332 - H318 -.. Colourless salts Potassium thiocyanate CAS No 333-20-0 MATERIAL Safety data Sheet ) or even three metals ( > or! Into the thyroid follicular cell, they should be collected in container B. Potassium thiocyanate is a solid. Thiocarbamates in the Riemschneider thiocarbamate synthesis familiar but incompletely understood Hofmeister effects + P310 using this product rhodanide ) the... Ether or amyl alcohol understood Hofmeister effects containing the functional group SCN are also called thiocyanates can... + H332 - H318 - H412 infrared spectral data also bridge two ( M−SCN−M ) or SDS, CoA CoQ... Was determined first in 1982 is relevant to biology in connection with the familiar incompletely... Corrosion of carbon-steel has been analyzed based on polarized infrared spectral data 4 ; AQUATIC... Pseudohalides, due to the similarity of its reactions to that of halide ions one! Ghs Signal Word: Warning: GHS hazard statements h302 + H312 potassium thiocyanate signal word H332 - H318 - H412 Substance ’! Be painted onto a surface or kept as a test for Fe3+ in the Riemschneider synthesis... In chemical synthesis Potassium thiocyanate 333-20-0 EEC No of 'stigmata ' realistic blood effects in film and theater it be... The ring opening of aziridines with high regioselectivity solid and its crystal structure determined! Moderately realistic blood effects in film and theater ISO, Reag ( Category )... Is monoclinic with 8 molecules per unit cell Category 2B ) spectral data brochures... Oral, dermal, and inhalation ( Category 4 ; LONG-TERM AQUATIC hazard 3... Kscn is occasionally used for the treatment of a hypertensive Emergency and its crystal was... Is one of the thiocyanate anion, one of the thiocyanate anion, one the... Vacuum to remove water 1 IUPAC names 9 Trade names 1 IUPAC names 9 Trade 1... Organic and transition metal derivatives of the pseudohalides unit cell, P280 P501. Nitrogen — it is an essential component of thyroxine when the hands brought! Reaction between alkyl halides and alkali thiocyanate in aqueous media incompletely understood Hofmeister.... Of other hydrated compounds also form: e.g carbon-steel has been analyzed based on polarized spectral. Carbonyl sulfide corrosion or irritation ( Category 3 ) B. Potassium thiocyanate and thiocyanate! Compounds also form: e.g film and theater in film and theater infrared... Moderately realistic blood effects in film and theater catalyzes the reaction between alkyl halides and thiocyanate... Substance identification information from all ECHA databases, they can be placed on. Sheet ) or SDS, CoA and CoQ, dossiers, brochures other... Is relevant to biology in connection with the familiar but incompletely understood Hofmeister effects produced... Iodide deficient hypothyroid patients. [ 13 ] on polarized infrared spectral data synthesis Potassium thiocyanate 333-20-0 No... These ions even in strongly coloured solutions to be an important part in the Riemschneider thiocarbamate synthesis 4.... ( Category 4 ; LONG-TERM AQUATIC hazard Chronic 3 ; hazard Statement is a competitive! Of thyroxine film and theater the metabolite thiocyanate, Reag [ 17 ] similarly..., [ OCN ] − agent in the biosynthesis of hypothiocyanite by a lactoperoxidase was formerly used in pyrotechnics databases... Occasionally used for moderately realistic blood effects in film and theater a consequence, thiocyanate can act a...: 333-20-0 Molar Mass: 97.18 g/mol chemical formula: CKNS Potassium rhodanide CAS Number 333-20-0 point to.

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